Just Accepted
Just Accepted
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ArticleHighly efficient separation of high-valent actinide ions from lanthanides via fractional crystallizationYarui Li, Huangjie Lu, Yingzhe Du, Jie Qiu*, Peng Lin*, Jian Lin*
ABSTRACT
This work presents a novel fractional crystallization strategy using 3,6-di-2-pyridyl-1,2,4,5-tetrazine, whose hydrolysis product selectively crystallizes U(VI) from Ln(III) with a record high separation factor of 756276 between U(VI) and Sm(III), enabling a highly efficient, energy-conscious approach for the partitioning of actinides from lanthanides. -
ArticleVisible-light responsive gold nanoparticle and nano-sized Bi2O3-x sheet heterozygote structure for efficient photocatalytic conversion of N2 to NH3Jijoe Samuel Prabagar, Kumbam Lingeshwar Reddy, Dong-Kwon Lim*
ABSTRACT
Plasmonic AuNP-nano-Bi2O3-x enhances visible-light-driven N2-to-NH3 conversion via oxygen vacancies, achieving a 2.6-fold photocatalytic boost of NH3 yield compared to AuNP-micro-Bi2O3-x. -
ArticleNovel open-framework chalcogenide photocatalysts: Cobalt cocatalyst valence state modulating critical charge transfer pathways towards high-efficiency hydrogen evolutionHaiyan Yin, Abdusalam Ablez, Zhuangzhuang Wang, Weian Li, Yanqi Wang, Qianqian Hu, Xiaoying Huang*
ABSTRACT
Co(II) and Co(0) were confined to the cavities of open-framework [In10S18]n6n- to modulate the critical photocatalytic steps for outstanding H2 evolution.
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ArticleSurface gallium hydride on Ga2O3 polymorphs: A comparative solid-state NMR studyHonglin Gao, Chunlin Yuan, Hongyu Chen, Aiyi Dong, Pan Gao*, Guangjin Hou*
ABSTRACT
Solid-state NMR spectroscopy has been applied in the characterization of reactive surface gallium hydride species on different Ga2O3 polymorphs, of which the configuration and structures have been unraveled. -
Mini-reviewAdvancements in photocatalytic hydrogen peroxide synthesis: overcoming challenges for a sustainable futureLiyang Qin, Luna Wu, Jinlin Long*
ABSTRACT
This review explores advancements in photocatalytic hydrogen peroxide synthesis, addressing key challenges, recent innovations in catalyst design, and future directions for sustainable, scalable production and industrial applications. -
ArticleMicroenvironment regulation of anode-electrolyte interface enables highly stable Zn anodesLin Peng, Xincheng Liang, Zelong Sun, Xingfa Chen, Dexin Meng, Renshu Huang, Qian Liu, Huan Wen, Shibin Yin*
ABSTRACT
The introduced methionine (Met) regulates the anode-electrolyte interface (AEI): Anchoring on Zn anode by amino/methylthio groups to form H2O-poor AEI, inhibiting hydrogen evolution reaction (HER); serving as a pH buffer to neutralize the generated OH− through electrostatic interaction, preventing by-products formation; capturing Zn2+ by carboxyl group of the anchored Met through electrostatic interaction to promote dense Zn deposition. -
ArticleHigh thermal conductivity in Ga2TeO6 crystals: Synergistic effects of rigid polyhedral frameworks and stereochemically inert cationsZiyi Liu, Feifei Guo*, Tingting Cao, Youxuan Sun, Xutang Tao, Zeliang Gao*
ABSTRACT
The new ternary oxide crystal Ga2TeO6 exhibits high κ due to the synergistic interplay between the rigid polyhedral frameworks and stereochemically inert cations, with κ values of 19.2 and 23.9 W m-1 K-1 along the a- and c-axes at 323 K. -
ArticleNano-flowers FeS/MoS2 composites as a peroxymonosulfate activator for efficient p-chlorophenol degradationXian-Rui Meng, Qian Chen, Mei-Feng Wu, Qiang Wu, Su-Qin Wang*, Li-Ping Jin, Fan Zhou, Ren-Li Ma*, Jian-Ping Zou*
ABSTRACT
The sulfur vacancies within FeS/MoS2 nanoflowers enhanced PMS activation, achieving 100% 4-CP degradation within 10 minutes, via exposing Mo(IV) sites and facilitating redox cycling of Fe and Mo active sites. -
ArticleTuning the eg* band broadening of the in-situ NiOOH by W doping for efficient biomass electrooxidationJinlv Wei, Jianlong Zhang, Huan Wen, Zhixiang Zhai, Fangyuan Guan, Zelong Sun, Jia Wu*, Shibin Yin*
ABSTRACT
In this work, W doping induces the structural distortion of the in situ formed NiOOH generated by reconstruction, effectively modulating its electronic states near the Fermi level, resulting in the broadening of the eg* band, which promotes electron transfer between the catalyst and HMF as well as the adsorption of HMF, significantly enhancing the activity of HMFOR. -
ArticleA metal azolate framework with small aperture for highly efficient ternary benzene/cyclohexene/cyclohexane separationXi Feng, Ding-Yi Hu, Zi-Jun Liang, Mu-Yang Zhou, Zhi-Shuo Wang, Wen-Yu Su, Rui-Biao Lin, Dong-Dong Zhou*, Jie-Peng Zhang
ABSTRACT
A novel metal‒azolate framework achieves high benzene selectivity from ternary C6 cyclic hydrocarbon mixtures, by virtue of the strong adsorption affinity for benzene and obvious differences in the kinetic diffusion. -
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ArticleMechanistic insights into acidic water oxidation by Mn(2,2′-bipyridine-6,6′-dicarboxylate)-based hydrogen-bonded organic frameworksShuai Liu, Wen Wu, Peili Zhang, Yunxuan Ding, Chang Liu, Yu Shan, Ke Fan*, Fusheng Li*
ABSTRACT
A hydrogen-bonded organic framework assembled by the complex of Mn2+ and 2,2′-bipyridine-6,6′-dicarboxylate was employed for OER under acidic conditions. The coupling of two Mn5+(O) species is the rate-determining step, which leads to this unusual pH dependence on the OER performance. -
ArticleRevealing the reactant adsorption role of high-valence WO3 for boosting urea-assisted water splittingWenjie Jiang, Zhixiang Zhai, Xiaoyan Zhuo, Jia Wu, Boyao Feng, Tianqi Yu, Huan Wen, Shibin Yin*
ABSTRACT
The construction of dual active sites of Ni3S2 and WO3 induces electron transfer from Ni3S2 to WO3 to optimize the adsorption of reactants, thus accelerating urea and water dissociation. -
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ReviewA review of plasma treatment on nano-microstructure of electrochemical water splitting catalystsTianli Hui, Tao Zheng*, Xiaoluo Cheng, Tonghui Li, Rui Zhang, Xianghai Meng, Haiyan Liu, Zhichang Liu, Chunming Xu
ABSTRACT
Recent progress of plasma treatment on water electrolysis catalysts is reviewed in terms of the impact on nano-microstructures. The challenges and opportunities of plasma technology in electrocatalysts fabrication are presented. -
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ArticleHigh stretchability and toughness of liquid metal reinforced conductive biocompatible hydrogels for flexible strain sensorsMengchen Liu, Yufei Zhang, Yi Xiao, Yang Wei, Meichen Bi, Huaide Jiang*, Yan Yu*, Shenghong Zhong*
ABSTRACT
In this study, EGaIn initiated the polymerization of LM/SA/P(AAm-co-BMA) hydrogel and enhanced the tensile strain up to 2800% and tensile strength up to 2.3 MPa. -
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Short CommunicationDonor-acceptor type organic cocrystals for deep-red circularly polarized luminescence and two-photon excited emissionJiawei Li, Cheng Chen*, Mingyan Wu*
ABSTRACT
Supramolecular donor–acceptor type organic cocrystals have successfully realized circular polarized luminescence as well as two-photon excited deep-red and near-infrared emission simultaneously. -
Short CommunicationOrganooxotin and cobalt/manganese heterometallic nanoclusters exhibiting single-molecule magnetismJun-Jie Fang, Yun-Peng Xie*, Xing Lu
ABSTRACT
Nine heterometallic Sn-Co/Mn nanoclusters (NCs) were synthesized, utilizing tBuPO32− modified Sn-oxo cluster as ligands. This study delves into the intricate self-assembly process of Sn-Co/Mn NCs, offering valuable insights for the development of novel single-molecule magnets.
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