Just Accepted
Just Accepted
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ReviewHighly active transition metal phosphides for urea oxidation: Design strategies, application advances, and perspectivesQimeng Zhu, Juan Xiao, Changyi Deng, Tingting Huang, Hui Ding, Li Zhang*, Guancheng Xu*
ABSTRACT
Highly active transition metal phosphides are engineered via morphology engineering and electronic structure modulation, enabling efficient urea oxidation and energy applications, with future prospects for sustainable catalysis. -
ArticlePeriodic Janus structure based on ionic covalent organic framework for selective removal of perfluoroalkyl substancesXiaojuan Sun, Ke Kong, Jun Liang, Dan Wang, Beibei Dong*, Ruihu Wang*
ABSTRACT
An ionic covalent organic framework (iCOF-DGCl) with hydrophobic aromatic moieties and hydrophilic guanidinium moieties was successfully prepared by using the Janus strategy. The iCOF exhibited fast kinetics, record capacities, high selectivity and good recyclability for the removal of toxic perfluorooctane sulfonate by cooperative adsorption. This work provides a tailor-made iCOF consisting periodic Janus structures for wastewater remediation.
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ArticlePrussian blue analogues derived MO/MFe2O4 (M = Ni, Cu, Zn) nanoparticles as a high-performance anode material for enhanced lithium storageQingyun Yang, Yue Ma, Quanyi Ye, Yiqing Liu, Yuhong Luo*, Yongbo Wu, Zhiguang Xu*, Xiaoming Lin*
ABSTRACT
Synthesis of porous MO/MFe2O4 (M = Ni, Cu, Zn) bimetallic oxide composites by Prussian blue template method to achieve high reversible capacity and long cycle stability. -
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ArticleDefective Ru1@Mo2COx single-atom catalyst for efficient thermal catalysis for ammonia synthesisYa Ren, Cong Zhang, Haiyan Wang, Jin-Xia Liang*, Chun Zhu*, Han-Shi Hu, Jun Li
ABSTRACT
MXene-based SAC Ru1@Mo2COx can effectively catalyze N2-to-NH3 through association mechanism. -
ArticleOptimizing the Schottky barrier in AuAg alloy decorated TiO2 nanofibers to enhance hot-electron-induced CO2 reductionNa Lu, Tingting Pang, Xuedong Jing, Yongan Zhu, Linqun Yu, Sining Ben, Yuchan Song, Shiwen Du, Wei Lu, Zhenyi Zhang*
ABSTRACT
Alloy-optimized Schottky barriers in AuAg/TiO2 nanofibers boost hot-electron-driven CO2 photoreduction, with mechanistic insights guiding rational plasmonic photocatalyst design. -
ArticleRegulating the oxygen vacancies in Ni-CexZr1-xO2/ZSM-5 to improve the long-term stability for methane dry reformingZhuwei Yang, Linsen Li, Yijie Lin, Xinyuan Tao, Xiao Liu, Lei Chen, Ming Ma, Li Lin*, Riguang Zhang*, Jiayuan Li, Zhao Jiang*
ABSTRACT
The suitable Ce/Zr ratio in Ni-CexZr1-xO2/ZSM-5 enhanced the long-term stability for DRM by increasing the strength and amount of Ni-O-M (M=Ce/Zr) species. -
ArticleNon-covalent interactions between adsorbed •OH species and UiO-66-NH2 for methane hydroxylationYun Zhou, Geqian Fang, Haiyan Wang, Wenjun Yu, Chun Zhu*, Jin-Xia Liang*, Jian Lin*
ABSTRACT
Non-covalent hydrogen bonds between •OH species and UiO-66-NH2 reduce the spin density distribution on (•OH)m, thereby diminishing the catalytic activity for DSOM. -
ReviewPolymeric carbon nitride for photocatalytic overall water splitting: Modification strategies and recent advancesABSTRACT
This review highlights the modification strategies of PCN in one-step and Z-scheme two-step excitation photocatalytic systems, aiming to provide guidance for the design of efficient photocatalysts for overall water splitting. -
![Metal-coordinate complexes (M = 3d, 4f) with enhanced circularly polarized luminescence in planar chiral pillar[5]arenes 2025.100626](/Site/default/Uploads/20250529/未标题-3[413].png "Metal-coordinate complexes (M = 3d, 4f) with enhanced circularly polarized luminescence in planar chiral pillar[5]arenes 2025.100626")
ArticleMetal-coordinate complexes (M = 3d, 4f) with enhanced circularly polarized luminescence in planar chiral pillar[5]arenesYu Tian, Yijun Lin, Siyu Deng, Yinghe Tan, Xuanyi Bie, Zhaoyang Chen, Pangkuan Chen*
ABSTRACT
We have synthesized pillar[5]arene-based chiral ligands (L1/L2) to coordinate with 3d/4f metal ions Zn2+, Eu3+ and Tb3+, leading to CPL-active metal complexes (Zn-L1, Eu-L1, Eu-L2, Tb-L2) with enhanced luminescence dissymmetry factor glum and CPL brightness BCPL. -
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ArticleBiocarbon-confined bimetallic FeCo metal-organic framework orthogonal nanosheet arrays for industry-level ethylene glycol oxidationMengjin Li, Tian Xia, Mengyu Wang, Yujie Peng, Sihan Zhang, Xueliang Jiang, Huan Yang*
ABSTRACT
Biocarbon-confined bimetallic MOF catalyst prepared by hydrothermal-thermal reduction method for industrial-scale electrocatalytic ethylene glycol oxidation coupled with hydrogen evolution. -
ArticleTopology guided construction of MOF by linking Zr-MOLs with perylene diimide motifs for photocatalytic oxidationChao Wei, Zi-Yi Zhao, Jing-Jing Li, Jinli Zhang, Ming Lu, Xiao-Qin Liu, Guoliang Liu*, Jiandong Pang, Lin-Bing Sun*
ABSTRACT
A MOF with a novel topology, constructed by linking Zr-MOLs and PDI motifs as confirmed by 3D electron diffraction, is developed for the first time for photocatalytic sulfide oxidation.
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ArticleNickel phosphide modified TiO2 nanotube arrays for efficient PEC water splitting H2 generationYang Yang, Yan-Xin Chen*, Ao-Sheng She, Hao-Yan Shi, Wen Chen, Wei Wang, Hai-Long Wang, Ke-Xian Li, Yi-Hu Pu, Wei-Hua Yang, Xiu-Mei Lin, Can-Zhong Lu*
ABSTRACT
Ni2P composite TiO2 nanotube arrays to form Schottky junctions exhibited an excellent hydrogen production of 182.96 μmol/cm2 during PEC water splitting at 1.23V vs. RHE under AM 1.5G illumination. -
ArticlePhotomechanical movements of a coordination polymer-based composite enable a reversible photocontrollable electrical switchQian Ren, Shu-Fen Zhang, Dong Liu*, Jian-Ping Lang*
ABSTRACT
A unique composite film featuring photomechanical movements functions an interesting reversible light-controlled circuit switch. -
ArticleStrategic metal substitution for enhanced visible-light-driven oxygen evolution in heterometallic MOFsCui Luo, Peng-Hui Li, Wei-Ming Liao*, Qia-Chun Lin, Xiao-Xiang Zhou, Jun He*
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Self-sensitized Fe2MCDDB MOFs enhance photocatalytic OER. Fe2NiCDDB achieves 125.3 μmol·g−1·h−1 oxygen via optimized charge separation and prolonged excited-state lifetime, enabling dual-functional MOF design for efficient water oxidation. -
ArticleType-I heterojunction photocatalysis: enhanced activity via ZnIn2S4/MnCo2O4.5 interfacial electric fieldsQiang Yu, Shuhan Sun, Xianming Jin, Ruiqiang Yan, Bingjing He, Nikolay Sirotkin, Alexander Agafonov*, Xianqiang Xiong*, Kangle Lv
ABSTRACT
Interfacial electric field driven ohmic-like charge transfer in type-I ZnIn2S4/MnCo2O4.5 heterojunction enables ultrahigh photocatalytic H2 evolution.
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ArticleCrystal orientation dependent charge transfer dynamics and interfacial water configuration boosting photoelectrocatalytic water oxidation to H2O2Yan Zhao, Zhenming Tian, Qisen Jia, Ting Yao, Jiashu Li, Yanan Wang, Xuejing Cui, Jing Liu*, Xin Chen*, Luhua Jiang*
ABSTRACT
Crystal orientation regulates electronic structure to influence the interface water configuration and thereby the selectivity of water oxidation. -
ArticleSynthesis, separation and structure of zinc coordination clusters: Proposal of an assembly-disassembly-reassembly process observed from ESI-MSHuang-Ling Lin, Meng-Zhen Xu, Tian-Ying Gu, Xing-Xing Shi, Mao Le, Zheng Yin, Ming-Hua Zeng*
ABSTRACT
The ESI-MS of an open cubane cluster Zn4L4 exhibits both disassembly and reassembly fragments, which guide and lead to the successful synthesis of three new crystalline clusters Zn1, Zn4L6 and Zn6L6 corresponding to those observed in the MS. The series of ESI-MS for the clusters and crystal/solution/gas structural information relevance reveal assemble mechanism and the complex of chemical reactions. -
ArticleFour tartaric acid-bridged tetra-europium(III)-containing antimonotungstate with catalytic oxidation of thioethers/alcoholsYuanping Jiang, Haoqi Liu, Jiawei Zhang, Luying Jiao, Xiaoling Lin*, Fuhua Zhang, Guoping Yang*
ABSTRACT
A novel dimeric four tartrate-bridged tetra-Eu(III)-included antimonotungstate was synthesized and exhibited excellent catalytic activity and reusability in the oxidation of thioethers/alcohols under green and mild conditions. -
ArticleStructural regulation of alkynyl-based covalent organic frameworks for multi-stimulus fluorescence sensingXinrui Chen, Wenjian Huang, Xiaoyang Zhao, Songyao Zhang, Xinrui Miao*
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ETBA-PYTA-COF was synthesized with ultra-high yield showing acidochromic, solvatochromic, and trace water sensitive properties based on intramolecular charge transfer effect. -
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ArticleNeodymium-doped hollow Ir/IrO2 nanospheres with low geometric iridium density enable excellent acidic water oxidation performanceXiaoqian Wei, Hanyu Gao, Tiantian Wang, Zijian Li, Yanru Geng, Guiping Zheng, Min Gyu Kim, Haeseong Jang*, Xien Liu*, Qing Qin*
ABSTRACT
Neodymium-doped Ir/IrO2 hollow structure significantly reduces the geometric loading of Ir in anodic catalyst layer of PEMWE without compromising catalytic layer performance. Nd doping induces critical interfacial Nd-O-Ir configurations that stabilize lattice oxygen, while intensified electron effect among mixed valent Ir that inhibits the overoxidation of Ir active sites, synergistically ensuring enhanced catalytic durability.
- Address: Fuzhou High & New Technology Industrial Zone, Shangjie, Minhou, Fuzhou, Fujian 350108, China
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- E-mail: cjsc@fjirsm.ac.cn