Just Accepted
Just Accepted
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ArticleCrystal orientation dependent charge transfer dynamics and interfacial water configuration boosting photoelectrocatalytic water oxidation to H2O2Yan Zhao, Zhenming Tian, Qisen Jia, Ting Yao, Jiashu Li, Yanan Wang, Xuejing Cui, Jing Liu*, Xin Chen*, Luhua Jiang*
https://doi.org/10.1016/j.cjsc.2025.100619
ABSTRACT
Crystal orientation regulates electronic structure to influence the interface water configuration and thereby the selectivity of water oxidation. -
ArticleSynthesis, separation and structure of zinc coordination clusters: Proposal of an assembly-disassembly-reassembly process observed from ESI-MShttps://doi.org/10.1016/j.cjsc.2025.100602
ABSTRACT
The ESI-MS of an open cubane cluster Zn4L4 exhibits both disassembly and reassembly fragments, which guide and lead to the successful synthesis of three new crystalline clusters Zn1, Zn4L6 and Zn6L6 corresponding to those observed in the MS. The series of ESI-MS for the clusters and crystal/solution/gas structural information relevance reveal assemble mechanism and the complex of chemical reactions. -
ArticleFour tartaric acid-bridged tetra-europium(III)-containing antimonotungstate with catalytic oxidation of thioethers/alcoholsYuanping Jiang, Haoqi Liu, Jiawei Zhang, Luying Jiao, Xiaoling Lin*, Fuhua Zhang, Guoping Yang*
https://doi.org/10.1016/j.cjsc.2025.100603
ABSTRACT
A novel dimeric four tartrate-bridged tetra-Eu(III)-included antimonotungstate was synthesized and exhibited excellent catalytic activity and reusability in the oxidation of thioethers/alcohols under green and mild conditions. -
ArticleStructural regulation of alkynyl-based covalent organic frameworks for multi-stimulus fluorescence sensingXinrui Chen, Wenjian Huang, Xiaoyang Zhao, Songyao Zhang, Xinrui Miao*
https://doi.org/10.1016/j.cjsc.2025.100604
ABSTRACT
ETBA-PYTA-COF was synthesized with ultra-high yield showing acidochromic, solvatochromic, and trace water sensitive properties based on intramolecular charge transfer effect. -
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ArticleNeodymium-doped hollow Ir/IrO2 nanospheres with low geometric iridium density enable excellent acidic water oxidation performanceXiaoqian Wei, Hanyu Gao, Tiantian Wang, Zijian Li, Yanru Geng, Guiping Zheng, Min Gyu Kim, Haeseong Jang*, Xien Liu*, Qing Qin*
https://doi.org/10.1016/j.cjsc.2025.100600
ABSTRACT
Neodymium-doped Ir/IrO2 hollow structure significantly reduces the geometric loading of Ir in anodic catalyst layer of PEMWE without compromising catalytic layer performance. Nd doping induces critical interfacial Nd-O-Ir configurations that stabilize lattice oxygen, while intensified electron effect among mixed valent Ir that inhibits the overoxidation of Ir active sites, synergistically ensuring enhanced catalytic durability. -
ArticleAll-sputtered protonic ceramic fuel cells based on flashlight-sintered thin-film Y:BaZrO3-δ electrolyteJiwon Baek, Junseo Youn, Hyoun-Myoung Oh, Jonghyuk Lee, Haesu Lee, Nguyen Q. Minh, Young-Beom Kim*, Yoon Ho Lee*, Taehyun Park*
https://doi.org/10.1016/j.cjsc.2025.100598
ABSTRACT
This study introduces a novel fabrication method for proton-conducting ceramic fuel cells (PCFCs) by combining magnetron sputtering and flashlight sintering, addressing barium evaporation and enhancing electrolyte crystallinity. -
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ArticleInvestigation of water structure and proton transfer within confined graphene by ab initio molecule dynamics and multiscale data analysisHeng-Su Liu, Xi-Ming Zhang, Ge-Hao Liang, Shisheng Zheng*, Jian-Feng Li*
https://doi.org/10.1016/j.cjsc.2025.100596
ABSTRACT
We integrate statistical analysis, graph theory, and persistent homology to unveil multi-scale structural features of confined water in graphene layers, providing new insights into hydrogen bond networks and proton transfer mechanisms. -
ArticleClose π-π stacking facilitated intermolecular charge separation in self-assembled perylene monoimide for photocatalytic hydrogen productionShuhong Wu, Wanying Han, Ying Wang*, Yan Zhuang, Hui Niu, Lurong Li, Junhui Wang, Yuan Liu, Huan Lin, Kaifeng Wu, Jinni Shen, Yingguang Zhang*, Michael K.H. Leung, Jinlin Long
https://doi.org/10.1016/j.cjsc.2025.100592
ABSTRACT
Perylene monoimide supramolecular (PM6A) was synthesized by introducing a pyridine-carboxylic acid group with high steric hindrance at the imide site, resulting in close π-π stacking. This tight π-πstacking facilitates the construction of smooth charge transfer channels, which allows for the complete separation of photogenerated charges into charge separation excitons (CSE). Consequently, PM6A exhibits a hydrogen evolution rate as high as 8100 μmo g-1 h-1. -
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ArticleA stable scandium(III) metal-organic framework with introduced nitrate ions for enhancing C2H6/C2H4 selectivity in the separation of MTO productsYajun Gao*, Xinyu Yang, Jian Su, Zhizhong Li
https://doi.org/10.1016/j.cjsc.2025.100576
ABSTRACT
A novel stabilized Sc-MOF with decorated nitrate ions based on [Sc3(μ2-OH)3(CO2)4O6]n inorganic chain was synthesized, which exhibits high C2H6/C2H4 adsorption selectivity comparable to many well-known C2H6-selective MOFs, making it a promising candidate for MTO product separation. -
ArticleA new selenide semiconductor NaMn3Ga3Se8 with strong second-harmonic generation and significant luminescence propertyQi Sun, Hongshan Wang, Linlin Liu, Zuxin Chen, Junjie Li*, Shilie Pan*
https://doi.org/10.1016/j.cjsc.2025.100591
ABSTRACT
A new selenide semiconductor NaMn3Ga3Se8 with strong second-harmonic generation and significant luminescence property has been rationally designed by a octahedron substitution strategy, and synthesized in experiment. -
ArticleHierarchical Pt/NiO hollow nanofibers for catalytic oxidation of HCHO at room temperatureXinyu Zeng, Zhuofan Zeng, Qingqing Hu, Kejun Liu, Lei Ming, Bei Cheng, Wang Wang*, Guoqiang Luo, Shaowen Cao*
https://doi.org/10.1016/j.cjsc.2025.100575
ABSTRACT
The synthesized Pt/NiO nanofibers feature a unique hollow structure and high specific surface area, exhibiting high HCHO oxidation performance at room temperature. -
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