A series of clip-shaped cationic molecular corners C1~C4 (C1 = [(bpy)₂Pd₂(L¹)₂]²⁺, C2 = [(dmbpy)₂Pd₂(L¹)₂]²⁺, C3 = (bpy)₂Pd₂(L²)₂]²⁺, C4 = (dmbpy)₂Pd₂(L²)₂]²⁺, bpy = 2,2-bipyridine, dmbpy = 4,4΄-dimethyl-2,2-bipyridine) were synthesized through dipalladium complexes [(bpy)₂Pd₂(NO₃)₂](NO₃)₂, [(dmbpy)₂Pd₂(NO₃)₂](NO₃)₂ and bifunctional pyrazole ligands 4-(3,4-dimethoxyphenyl)-3,5-dimethyl-1H-pyrazol (HL¹) and 4,4΄-(5-(1H-pyrazol-4-yl)-1,3-phenylene)dipyridine (HL²). Complexes C1~C4 were characterized by ¹H and ¹³C NMR, electrospray ionization mass spectrometry (ESI-MS), elemental analysis, and IR spectroscopy. The X-ray diffraction analysis of C1∙2NO₃⁻ revealed a Pd₂ dimetallic clip-shaped structure which was synthesized by two bifunctional ligands doubly bridged by the [(bpy)Pd]₂ dimetal units. Additionally, all of the complexes with NO₃⁻ as counter anions exhibited high-efficiency catalytical performance in the Suzuki-coupling reaction attributed to the tunable impact and weak dinuclear Pd(II)···Pd(II) intramolecular bonding interaction.