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Synergized oxygen vacancies with Mn2O3@CeO2 heterojunction as high current density catalysts for Li–O2 batteries
Renshu Huang, Jinli Chen, Xingfa Chen, Tianqi Yu, Huyi Yu, Kaien Li, Bin Li*, Shibin Yin* Submit a Manuscript
Pd-based nanocatalysts for oxygen reduction reaction: Preparation, performance, and in-situ  characterization

Guan-Nan Xing, Di-Ye Wei, Hua Zhang, Zhong-Qun Tian*, Jian-Feng Li*

Chin. J. Struct. Chem., 2023, 42: 100021. DOI: 10.1016/j.cjsc.2023.100021

November 15, 2023

Pd-based nanocatalyst; Oxygen reduction reaction; Electrocatalysis; In-situ characterization

ABSTRACT

Electrochemical energy devices such as fuel cells have received extensive concern in recent decades. However, the commercial applications of fuel cells have been restricted by the slow kinetics of oxygen reduction reaction (ORR). Pd-based fuel cell catalysts are strong candidates for enhanced ORR activities, especially under alkaline conditions. Therefore, extensive exploration has been made to improve the performance of Pd-based nanocatalysts for oxygen reduction reaction. This paper reviews the research progress of preparation, electrocatalytic performance, and in-situ characterization of various Pd-based oxygen reduction catalysts, from zero-dimensional nanoparticles, to one-dimensional nanowires, to two-dimensional nanosheets, and to Pd single-atom catalysts. It may provide some help for improving the activity of Pd-based catalysts and understanding the reaction mechanisms and structure-activity relationships.


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