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A classification scheme for inorganic cluster compounds based on their electronic structures and bonding characteristics
Zhenyang Lin*
https://doi.org/10.1016/j.cjsc.2024.100254
Inorganic cluster compounds; Structure and bonding; Electron counting rules; Superatomic clusters
ABSTRACT
A novel classification scheme for inorganic cluster compounds is presented based on the characteristics of their electronic structures. In the classification scheme, five distinct categories have been introduced, including Jellium clusters, Wadian clusters, electron-precise clusters, π-donor ligated metal-metal bonded clusters, and antiferromagnetically coupled high-spin metal clusters.
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