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A flexible-robust MOF for efficient purification of perfluoropropane

Lixian Cai, Yingxiang Ye*

https://doi.org/10.1016/j.cjsc.2024.100368

ABSTRACT

In summary, this work presented a compelling study of employing a flexible-robust MOF to achieve highly efficient C3F6/C3F8 separation through a temperature-modulated gating mechanism. Here, they emphasize the important role of temperature-dependent gate-opening adsorption behavior and elucidate the host-guest interactions through a combination of experimental, single-crystal structural, and theoretical computational analyses. This finding provides a valuable idea for harnessing the flexibility of porous adsorbents and distinct host-guest interactions to effectively separate important and challenging industrial gas mixtures.

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