Recent advances in non-π-conjugated nonlinear optical sulfates with deep-UV absorption edge
Xu Chen, Yanqiang Li, Junhua Luo, Sangen Zhao* Submit a Manuscript
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Perspective“Free-oxygen”: A promising functional unit for strengthening electron-phonon coupling effectFei Liang*
Chin. J. Struct. Chem., 2023, 42: 100064. DOI: doi.org/10.1016/j.cjsc.2023.100064
March 15, 2023
ABSTRACT
Multiphonon coupling has been demonstrated to an effective strategy to extended lasing wavelengths. The ‘free-oxygen’ motif is a good functional unit for strengthening such interaction between active ions and their surrounding lattices. -
Short CommunicationStructural design and characterization of a new chalcone molecular derivative crystal DMNC with high second-order nonlinear coefficientJinkang Ma, Siyuan Hu, Xueting Mu, Rui Chen, Kun Meng, Bing Teng*, Lifeng Cao*, Degao Zhong*
Chin. J. Struct. Chem., 2023, 42: 100058. DOI: 10.1016/j.cjsc.2023.100058
March 15, 2023
ABSTRACT
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ReviewFluorooxoborates: A precious treasure of deep-ultraviolet nonlinear optical materialsHongkang Su, Ziting Yan, Xueling Hou*, Min Zhang*
Chin. J. Struct. Chem., 2023, 42: 100027. DOI: 10.1016/j.cjsc.2023.100027
March 15, 2023
Fluorooxoborates; Deep-ultraviolet (DUV); Nonlinear optical crystals; Second harmonic generation
ABSTRACT
The excellent functional units in fluorooxoborates and their various assembly methods are the treasure for searching for the next generation of deep ultraviolet nonlinear optical crystals. At present, many fluorooxoborates with excellent performance have emerged.
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ReviewSalt-inclusion chalcogenides: Double functional moieties design strategy toward excellent nonlinear optical materialsChao-Hong Xie, Bin-Wen Liu*, Guo-Cong Guo*
Chin. J. Struct. Chem., 2023, 42: 100029. DOI: 10.1016/j.cjsc.2023.100029
March 15, 2023
Salt-inclusion chalcogenide; Nonlinear optical material; Host and guest parts; Tructural crystal
ABSTRACT
Salt-inclusion chalcogenide offers the double functional motifs design strategy that settles the mutual contradiction between strong second-harmonic generation intensity and wide band gap (corresponding to high laser-deduced damage threshold) in infrared nonlinear optical materials. -
ReviewRecent advances of inorganic phosphates with UV/DUV cutoff edge and large second harmonic responseBoxuan Zhang, Zhaohui Chen*
Chin. J. Struct. Chem., 2023, 42: 100033. DOI: 10.1016/j.cjsc.2023.100033
March 15, 2023
Phosphate; NLO properties; UV/DUV; Structure-property
ABSTRACT
This review analyzes the structure-property relationship of the representative UV/ DUV phosphates, and the microscopic mechanism to achieve a balance between the short absorption edge and large SHG response is summarized. -
ReviewRecent progress in ultraviolet and deep-ultraviolet nonlinear optical aluminoboratesQing-Fen Li, Wei-Feng Chen, You-Zhao Lan, Jian-Wen Cheng*
Chin. J. Struct. Chem., 2023, 42: 100036. DOI: 10.1016/j.cjsc.2023.100036
March 15, 2023
Aluminum borate; Nonlinear optical; Ultraviolet; Deep-ultraviolet
ABSTRACT
The combination of AlOn (n = 4, 5, 6) polyhedra or their fluorinated analogues with different polyborate anions leads to a rich variety of crystalline aluminoborates. In this review, we summarize the recent developments of UV and deep-UV nonlinear optical aluminoborates. -
ReviewRecent advances in non-π-conjugated nonlinear optical sulfates with deep-UV absorption edgeXu Chen, Yanqiang Li, Junhua Luo, Sangen Zhao*
Chin. J. Struct. Chem., 2023, 42: 100044. DOI: 10.1016/j.cjsc.2023.100044
March 15, 2023
Crystal structures; Structure-property relationships; Deep-UV; NLO crystals; Sulfates
ABSTRACT
This review summerizes the crystal structural units of recently reported non-π-conjugated NLO sulfates with deep-UV absorption edge and discuss how to achive the balance between SHG efficiency, birefringence, and short UV absorption edge by structural design and synthesis.
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