A two-dimensional (2
D) organic-inorganic hybrid
perovskite (OIHP) material is considered as a promising candidate for a long-term
stable photodetector owing to its outstanding phase and environmental stability. Herein, we demonstrate a
perovskite photodiode based on the DJ phase 2
D perovskite (PDA)(MA)
n-1Pb
nI
3n+1 (where PDA is 1,3-propylenediamine, MA is methylamine, nominal
n = 4). The best-performance device
exhibits a high detectivity of 4.57 × 10
11 Jones, a responsivity of
0.25 A×W
−1 at 480 nm, a low dark current density
of 9.60 × 10
−4 mA×cm
−2, and a
remarkable on/off ratio of 3.10 × 10
5. The unencapsulated device can
maintain 95% of the initial photocurrent density after 90 days under an ambient
atmosphere with relative humidity (RH) of 65%, demonstrating its improved
stability than the 3
D counterpart. The excellent stability of the
photodiode based on 2
D perovskite promises its bright commercial
application future.