Long-term Stable 2D Dion-Jacobson Phase Perovskite Photodiode with Low Dark Current and High On/off Ratio

GU Hao, CHEN Shan-Ci and ZHENG Qing-Dong*

Chin. J. Struct. Chem. 2021, 40, 1621-1630  DOI: 10.14102/j.cnki.0254-5861.2011-3200

December 15, 2021

two-dimensional perovskite, Dion-Jacobson, photodiode, on/off ratio, stability

ABSTRACT

A two-dimensional (2D) organic-inorganic hybrid perovskite (OIHP) material is considered as a promising candidate for a long-term stable photodetector owing to its outstanding phase and environmental stability. Herein, we demonstrate a perovskite photodiode based on the DJ phase 2D perovskite (PDA)(MA)n-1PbnI3n+1 (where PDA is 1,3-propylenediamine, MA is methylamine, nominal n = 4). The best-performance device exhibits a high detectivity of 4.57 × 1011 Jones, a responsivity of 0.25 A×W−1 at 480 nm, a low dark current density of 9.60 × 10−4 mA×cm−2, and a remarkable on/off ratio of 3.10 × 105. The unencapsulated device can maintain 95% of the initial photocurrent density after 90 days under an ambient atmosphere with relative humidity (RH) of 65%, demonstrating its improved stability than the 3D counterpart. The excellent stability of the photodiode based on 2D perovskite promises its bright commercial application future.

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