Chin. J. Struct. Chem. 2022, 41, 2212060-2212069 DOI: 10.14102/j.cnki.0254-5861.2022-0179
December 2, 2022
high internal phase emulsion (HIPE),
metal-organic frameworks (MOFs), adsorption and separation, heterogeneous
catalysis, bioengineering
ABSTRACT
As promising engineering materials for green and sustainable processes,
porous metal-organic framework (MOF)-polymer composites show great potential
in applications, including adsorption, separation, catalysis, and
bioengineering. Owing to the mild and scalable operation, porous polymeric
materials derived from high internal phase emulsion templates (polyHIPE) have
received great interests in recent decades. In this contribution, research
progress of the preparation of porous MOF@polyHIPE composites and their
applications are reviewed, highlighting how can MOF particles be shaped by HIPE
templates, in particular the polymerizable ones. Four different emulsion
templates stabilized by MOFs and the applications of corresponding MOF@polyHIPE are included. Hopefully, both the
state-of-art and future directions present herein can give rise to the
development of high-performance porous MOF@polyHIPEs.