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Ultrathin ZnIn2S4 Nanosheets Supported Metallic Ni3FeN for Photocatalytic Coupled Selective Alcohol Oxidation and H2 Evolution

Mengqing Li, Weiliang Qi, Jiuyang Yu, Lijuan Shen, Xuhui Yang, Siqi Liu* and Min-Quan Yang*

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Recent Developments of Dinitrogen Activation on Metal Complexes and Clusters

Xue-Lu Ma, Meng Li, Jun-Bo Lu, Cong-Qiao Xu and Jun Li*

Chin. J. Struct. Chem. 2022, 41, 2212080-2212088  DOI: 10.14102/j.cnki.0254-5861.2022-0197

December 2, 2022

dinitrogen activation, binding mode, dinitrogen complex, metal cluster, synergistic mechanism

ABSTRACT

Dinitrogen (N2) is the major component of the atmosphere and many factors bring about dinitrogen inertness with low reactivity. Dinitrogen activation on metal complexes and clusters under ambient condition is the long-standing goal in the modern chemistry. In this review, an attempt has been made to survey the mechanistic aspects of dinitrogen activation and functionalization based on different coordination binding modes of dinitrogen. Our goal is to provide a comprehensive survey of dinitrogen activation in order to guide the relevant research in the future.


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