Cover Picture
Ultrathin ZnIn2S4 Nanosheets
Supported Metallic Ni3FeN for Photocatalytic Coupled Selective
Alcohol Oxidation and H2 Evolution
Mengqing Li, Weiliang Qi, Jiuyang Yu, Lijuan Shen, Xuhui Yang, Siqi Liu* and Min-Quan Yang*
Submit a ManuscriptRecent Developments of Dinitrogen Activation on Metal Complexes and Clusters
Xue-Lu Ma, Meng Li, Jun-Bo Lu, Cong-Qiao Xu and Jun Li*
Chin. J. Struct. Chem. 2022, 41, 2212080-2212088 DOI: 10.14102/j.cnki.0254-5861.2022-0197
December 2, 2022
dinitrogen activation, binding mode, dinitrogen complex, metal cluster, synergistic mechanism
ABSTRACT
Dinitrogen (N2) is the major component of the atmosphere and many factors bring about dinitrogen inertness with low reactivity. Dinitrogen activation on metal complexes and clusters under ambient condition is the long-standing goal in the modern chemistry. In this review, an attempt has been made to survey the mechanistic aspects of dinitrogen activation and functionalization based on different coordination binding modes of dinitrogen. Our goal is to provide a comprehensive survey of dinitrogen activation in order to guide the relevant research in the future.
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