Just Accepted
Jiajing Wu, Ru-Ling Tang, Sheng-Ping Guo*
https://doi.org/10.1016/j.cjsc.2024.100291
ABSTRACT
In summary, theoretical
calculations and experimental analysis show that both π-conjugated organic
cation with local polarity and tetravalent rare-earth cerium cations without
lone pair electrons could be considered as good FBU for achieving a balance
between SHG response and LIDT of metal halides, providing some unprecedented
opportunities for designing novel NLO crystals. Additionally, integrating of a
high coordination number of Zr4+ cation and a
higher proportion of F atom would facilitate the acquisition
of shorter UV
cutoff edges. Therefore, we believe that if we can control the order
arrangement and density of these microscopic groups in the crystal structure, the vigorous development of laser technology and its related
fields will be
undoubtedly promoted.