Jia-hui Li, Jinkai Qiu, Cheng Lian*
Chin. J. Struct. Chem., 2025, 44(1), 100381. DOI: 10.1016/j.cjsc.2024.100381
January 1, 2025
ABSTRACT
The ionic
conductivity in high-performance solid-state electrolytes can reach 10-2 S cm-1 that is equivalent to the conductivity of
liquid electrolytes, which has greatly promoted the vigorous development of
quasi-solid-state batteries and all-solid-state batteries. Whether in polymer
electrolytes, inorganic crystal electrolytes or composite solid electrolytes,
the rapid transport mechanism of lithium-ion is the essential criterion used to
guide high-performance solid electrolyte design. A comprehensive understanding
of the rapid lithium-ion transport mechanism requires to focus on the
structural characteristics of the material and developing relevant simulation
methods to reveal the structure-activity relationship in rapid ion transport.