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Hydrogen spillover enhances the selective hydrogenation of α,β-unsaturated aldehydes on the Cu–O–Ce interface
Jinyuan Cui, Tingting Yang, Teng Xu, Jin Lin, Kunlong Liu*, Pengxin Liu* Submit a Manuscript
Hydrogen spillover enhances the selective hydrogenation of α,β-unsaturated aldehydes on the Cu–O–Ce interface
Jinyuan Cui, Tingting Yang, Teng Xu, Jin Lin, Kunlong Liu*, Pengxin Liu* Submit a Manuscript
Rational design of metal-metal hydroxide interface for efficient electrocatalytic oxidation of biomass-derived platform molecules
Yuchen Wang*, Zhenhao Xu, Kai Yan
Chin. J. Struct. Chem., 2025, 44(1), 100418. DOI: 10.1016/j.cjsc.2024.100418
January 1, 2025
ABSTRACT
In summary, the reported work proposes Pd/Ni(OH)2 catalysts with rich Ni2+-O-Pd interfaces for low-potential HMFOR with ∼100% FDCA selectivity. At Ni2+-O-Pd interfaces, efficient HMFOR originates from the formation of abundant OH∗ and the decreased activation energy of C–H bonds. It is proved that the construction of metal-metal hydroxide interfaces is very effective for efficient electrocatalytic oxidation of biomass-derived platform molecules. This work provides comprehensive theoretical insights for highly selective synthesis of high-value biomass-derived products at low potential through electrocatalytic oxidation technique.
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