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Recent Advances in C2 Gases Separation and Purification by Metal-Organic Frameworks

Zhengyi Di, Xinjing Zheng, Yu Qi, Heng Yuan and Cheng-Peng Li*

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A Review on Crystalline Porous MOFs Materials in Photocatalytic Transformations of Organic Compounds in Recent Three Years

Hao Zhang, Ru Sun, Da-Cheng Li and Jian-Min Dou*

Chin. J. Struct. Chem. 2022, 41,  2211071-2211083  DOI: 10.14102/j.cnki.0254-5861.2022-0140

October 31, 2022

metal-organic frameworks, porous materials, photocatalytic reaction, organic transformations

ABSTRACT

Metal-organic frameworks (MOFs) have always been the focus of chemists due to their diverse structures, adjustable pore size and high stability since they came into being. In recent years, as one of the most significant applications of MOFs porous materials, photocatalytic organic compounds transformation has made full-grown progress both in the preparation of the catalysts themselves and in the scope of specific applications. Herein, we summarize the research progress of MOFs catalysts for photocatalytic transformations of organic compounds in recent three years. Some outstanding works on the preparation and synthesis strategies of photocatalysts are introduced firstly, including internal optimization and modification of MOFs, POM@MOF composite and core-shell MOF@COF hybrids. The second part is about the application of diverse types of organic reactions, including dual-function organic reactions, catalytic oxidation reactions, comprehensive utilization of CO2 and degradation of organic pollutants. Besides, the development opportunities and some problems to be solved in this field are proposed.





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