Synthesis and Crystal Structure of a Copper(II) Complex with Funnel-like Ligand Based on Calix[6]arene
WANG Yi-Feng and SHU Mou-Hai*
Chin. J. Struct. Chem. 2022, 41, 2203186-2203192 DOI: 10.14102/j.cnki.0254-5861.2011-3312
March 15, 2022
Cu(II) complex, crystal structure, calix[6]arene, host-guest interaction
ABSTRACT
The preparation method of a funnel like ligand
derived from calix[6]arene and tris(2-pyridyl-
methyl)anime has been improved. The Cu(II) complex was
obtained and characterized by ESI-MS, EPR, UV-Vis spectra and crystallographic
analysis. In the complex, a guest acetonitrile molecule is introduced into the
cavity of the ligand host via the coordination with Cu(II) center.
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