Coordination polymers with structurally designable and energy, fluorescence, electrical etc. properties, are expected to become the next generation of multifunctional materials. A new compound, Zn(OAc)SPhNH (HSPhNH₂ = 4-aminophenol), was hydrothermally synthesized using 4-aminophenol as template and balance anion. The single-crystal X-ray diffraction showed a two-dimensional (2D) structure constructed of Zn(OAc)⁺ and SPhNH^-. This compound exhibited typical semiconductive behavior, whose conductivity increased with the raise of temperature. Moreover, the conductivity was positively correlated with humidity. The compound also showed blue light emission property, which indicates great potential applications in light-emitting diodes.