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Structure and assembly mechanism of high-nuclear lanthanide-oxo clusters

Hai-Ling Wang, Zhong-Hong Zhu*, Hua-Hong Zou*

https://doi.org/10.1016/j.cjsc.2024.100372

ABSTRACT

In summary, the proposal and development of the ligand chelation method not only promotes the progress of lanthanide cluster crystal engineering, but also provides opportunities for the construction of highly stable lanthanide clusters. In addition, the introduction of multidentate chelating ligands promotes the self-assembly mechanism of lanthanide clusters and takes a big step towards the controllable construction of lanthanide clusters of specific shapes.


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