One-dimensional
nanostructures (1D) with short ion diffusion distance and fast ion transport
path are excellent for lithium-ion batteries (LIBs). However, the nature of
layered transition metal dichalcogenides makes it difficult to form 1D nanohybrids.
Here, the MoTe
2 nanorods with an average diameter of 100-200 nm
and length of 1-3 μm encapsulated by reduced graphene oxide (MoTe
2/rGO)
have been fabricated via in-situ reaction of GO coated Mo
3O
10(C
2H
10N
2)
nanowires with Te under Ar/H
2 atmosphere. When applied as anode of
LIBs, the MoTe
2/rGO delivers a high reversible capacity (637 mA h g
-1 after 100 cycles at 0.2
A g
-1), good rate capability (374 mA h g
-1 at 2 A g
-1)
and excellent stability (360 mA h g
-1 after 200 cycles at 0.5 A g
-1),
which surpasses bare MoTe
2 nanorods and bulk MoTe
2 crystallite. Furthermore, a lithium-ion full cell constructed by coupling MoTe
2/rGO
anode and LiCoO
2 cathode shows a capacity of 105 mA h g
-1 at 0.1 C. The enhanced performance mainly benefits from the advantages of 1D
nanostructure, and meanwhile the rGO thin layers are able to improve the
conductivity and maintain the structural stability. This work provides a simple
pathway for the synthesis of 1D TMDs nanostructures for energy storage and
conversion.