Graphene Oxide/Fe3O4 Magnetic Nanocomposites for Efficient Recovery of Indium

WANG Ling-Hang, QIU Zhi-Hua and CHI Li-Sheng*

Chin. J. Struct. Chem. 2021, 40, 1423-1432  DOI: 10.14102/j.cnki.0254-5861.2011-3161

December 15, 2021

adsorbent, graphene oxide, Fe3O4 magnetic nanoparticles (NPs), nanocomposites, In(Ⅲ)

ABSTRACT

Adsorbent has been widely used for the recovery and enrichment of rare metals from waste water. Herein, a graphene-based adsorbent, graphene oxide/Fe3O4 (GO/Fe3O4) nanocomposite, was prepared by a facile hydrothermal method, and characterized by X-ray diffraction, Scanning Electron Microscope, X-ray Photoelectron Spectroscopy, Zeta potential and magnetization. The material has been explored for the recovery of In from simulated waste water. The test results show that the nanocomposite has a reasonable adsorption capacity on indium in a wide pH range, e.g., the adsorption percent and quantity of In(Ⅲ) from the aqueous solutions at pH = 4 and C0 = 50 mg·L−1 are 91% and 43.98 mg·L−1, respectively. In addition, the nanocomposites maintain a 75.5% cycling capacity and a 71% removal efficiency after five continuous cycles due to their novel properties of high specific surface area and superparamagnetism. The pseudo-second-order adsorption model can be used to interpret the kinetic data. High adsorption efficiency and good reusability can make the nanocomposite a promising adsorbent for recovery of In(Ⅲ).

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