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Pyrene-benzothiadiazole-based Polymer/CdS2D/2D Organic/Inorganic Hybrid S-scheme Heterojunctionfor Efficient Photocatalytic H
2Evolution

Ruiqi Gao, Huan He, Junxian Bai, Lei Hao, Rongchen Shen*, Peng Zhang, Youji Li and Xin Li*
The blue cover, together with elements such as blisters, lightning and the sun, highlights the good prospect of this new type of heterojunction as a photocatalytic material. The "S" shaped dragon depicted by the element of water rises from the bottom, implying that the dragon gets water and magically turns water into green hydrogen over organic/inorganic S-type heterojunction photocatalyst under sunlight irradiation.


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Ag2S Quantum Dots Decorated on Porous Cubic-CdS Nanosheets-Assembled Flowers for Photocatalytic CO2 Reduction

Wei Fu, Jiajie Fan and Quanjun Xiang*

Chin. J. Struct. Chem. 2022, 41, 2206039-2206047  DOI: 10.14102/j.cnki.0254-5861.2022-0090

June 20, 2022

CdS nanosheet, Ag2S quantum dots (QDs), assembled flower structure, composite materials, photocatalytic CO2 reduction

ABSTRACT

The production of renewable fossil fuels such as CH4 and CO by photocatalytic CO2 reduction has attracted more and more attention. However, single photocatalyst is less efficient for photocatalytic reduction of CO2 due to the fast recombination of photogenerated electron pairs. Herein, we successfully prepare CdS-Ag2S composite by assembling the Ag2S QDs cocatalyst on the surface of CdS nanosheet-assembled flower through oil-bath solvothermal method. This composite is prepared through a simple self-assembly strategy using cadmium chloride, ammonia and thiourea as precursors of the CdS nanosheet-assembled flower and silver nitrate and 3-mercaptopropionic acid as the precursors of Ag2S QDs. The average diameter of Ag2S QDs is apparently 6.0 nm. The light absorption edge of the composite is at around 560 nm, with the corresponding band gap at 2.14 eV. The CdS-Ag2S QDs composite with 5 wt% Ag2S QDs loaded achieves CO evolution rate of 16.6 μmol·g-1·h-1 without noble-metal cocatalysts. This strengthened photocatalytic performance and photocatalytic stability were attributed to the energy band broadening of Ag2S QDs caused by quantum size effect and the large specific surface area due to the assembled flower. The mechanism underlying the enhanced photocatalytic CO2 reduction activity is further proposed. This study demonstrates that semiconductor-based quantum dots are strong candidates for excellent cocatalysts in photocatalysis.

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