High thermal conductivity in Ga2TeO6 crystals: Synergistic effects of rigid polyhedral frameworks and stereochemically inert cations
Ziyi Liu, Feifei Guo*, Tingting Cao, Youxuan Sun, Xutang Tao, Zeliang Gao* Submit a Manuscript
April 2025Vol. 44, Issue 4
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Short CommunicationOrganooxotin and cobalt/manganese heterometallic nanoclusters exhibiting single-molecule magnetismJun-Jie Fang, Yun-Peng Xie*, Xing Lu*
Chin. J. Struct. Chem., 2025, 44(4), 100515. DOI: 10.1016/j.cjsc.2025.100515
April 1, 2025
ABSTRACT
Nine heterometallic Sn-Co/Mn nanoclusters (NCs) were synthesized, utilizing tBuPO32− modified Sn-oxo cluster as ligands. This study delves into the intricate self-assembly process of Sn-Co/Mn NCs, offering valuable insights for the development of novel single-molecule magnets.
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ArticleMicroenvironment regulation of anode-electrolyte interface enables highly stable Zn anodesLin Peng, Xincheng Liang, Zelong Sun, Xingfa Chen, Dexin Meng, Renshu Huang, Qian Liu, Huan Wen, Shibin Yin*
Chin. J. Struct. Chem., 2025, 44(4), 100542. DOI: 10.1016/j.cjsc.2025.100542
April 1, 2025
Aqueous zinc ion batteries; Zn anodes; Electrolyte additives; Anode-electrolyte interface; Capture effect; pH buffer
ABSTRACT
The introduced methionine (Met) regulates the anode-electrolyte interface (AEI): Anchoring on Zn anode by amino/methylthio groups to form H2O-poor AEI, inhibiting hydrogen evolution reaction (HER); serving as a pH buffer to neutralize the generated OH− through electrostatic interaction, preventing by-products formation; capturing Zn2+ by carboxyl group of the anchored Met through electrostatic interaction to promote dense Zn deposition. -
ArticleHigh thermal conductivity in Ga2TeO6 crystals: Synergistic effects of rigid polyhedral frameworks and stereochemically inert cationsZiyi Liu, Feifei Guo*, Tingting Cao, Youxuan Sun, Xutang Tao, Zeliang Gao*
Chin. J. Struct. Chem., 2025, 44(4), 100544. DOI: 10.1016/j.cjsc.2025.100544
April 1, 2025
High thermal conductivity; Oxide functional crystal; Polyhedral frameworks; Stereochemically inert cations
ABSTRACT
The new ternary oxide crystal Ga2TeO6 exhibits high κ due to the synergistic interplay between the rigid polyhedral frameworks and stereochemically inert cations, with κ values of 19.2 and 23.9 W m-1 K-1 along the a- and c-axes at 323 K. -
ArticleNovel open-framework chalcogenide photocatalysts: Cobalt cocatalyst valence state modulating critical charge transfer pathways towards high-efficiency hydrogen evolutionHaiyan Yin, Abdusalam Ablez, Zhuangzhuang Wang, Weian Li, Yanqi Wang, Qianqian Hu*, Xiaoying Huang
Chin. J. Struct. Chem., 2025, 44(4), 100560. DOI: 10.1016/j.cjsc.2025.100560
April 1, 2025
Open-framework Metal sulfide; Ion exchange; Cobalt cocatalyst; Valence state; Charge transfer; Photocatalytic hydrogen evolution
ABSTRACT
Co(II) and Co(0) were confined to the cavities of open-framework [In10S18]n6n- to modulate the critical photocatalytic steps for outstanding H2 evolution.
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ArticleSurface gallium hydride on Ga2O3 polymorphs: A comparative solid-state NMR studyHonglin Gao, Chunlin Yuan, Hongyu Chen, Aiyi Dong, Pan Gao*, Guangjin Hou*
Chin. J. Struct. Chem., 2025, 44(4), 100561. DOI: 10.1016/j.cjsc.2025.100561
April 1, 2025
Gallium hydride; Solid-state NMR; J-coupling; Surface configuration; Dissociation mechanism
ABSTRACT
Solid-state NMR spectroscopy has been applied in the characterization of reactive surface gallium hydride species on different Ga2O3 polymorphs, of which the configuration and structures have been unraveled. -
ArticleHighly efficient separation of high-valent actinide ions from lanthanides via fractional crystallizationYarui Li, Huangjie Lu, Yingzhe Du, Jie Qiu*, Peng Lin*, Jian Lin*
Chin. J. Struct. Chem., 2025, 44(4), 100562. DOI: 10.1016/j.cjsc.2025.100562
April 1, 2025
Lanthanide; Actinide; Uranium; Separation; Crystallization
ABSTRACT
This work presents a novel fractional crystallization strategy using 3,6-di-2-pyridyl-1,2,4,5-tetrazine, whose hydrolysis product selectively crystallizes U(VI) from Ln(III) with a record high separation factor of 756276 between U(VI) and Sm(III), enabling a highly efficient, energy-conscious approach for the partitioning of actinides from lanthanides. -
ArticleVisible-light responsive gold nanoparticle and nano-sized Bi2O3-x sheet heterozygote structure for efficient photocatalytic conversion of N2 to NH3Jijoe Samuel Prabagar, Kumbam Lingeshwar Reddy, Dong-Kwon Lim*
Chin. J. Struct. Chem., 2025, 44(4), 100564. DOI: 10.1016/j.cjsc.2025.100564
April 1, 2025
Photocatalyst; Gold nanoparticle; Bismuth oxide; Oxygen vacancy; Nitrogen fixation
ABSTRACT
Plasmonic AuNP-nano-Bi2O3-x enhances visible-light-driven N2-to-NH3 conversion via oxygen vacancies, achieving a 2.6-fold photocatalytic boost of NH3 yield compared to AuNP-micro-Bi2O3-x. -
Mini-reviewAdvancements in photocatalytic hydrogen peroxide synthesis: overcoming challenges for a sustainable futureLiyang Qin, Luna Wu, Jinlin Long*
Chin. J. Struct. Chem., 2025, 44(4), 100545. DOI: 10.1016/j.cjsc.2025.100545
April 1, 2025
Hydrogen peroxide production; Green chemistry; Solar energy; Sustainable synthesis
ABSTRACT
This review explores advancements in photocatalytic hydrogen peroxide synthesis, addressing key challenges, recent innovations in catalyst design, and future directions for sustainable, scalable production and industrial applications.
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