Just Accepted
Just Accepted
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ArticleUnveiling the dynamic reconstruction mechanism of NiMo alloy for enhanced 5-hydroxymethylfurfural electrooxidationShuaiqin Huang, Huan Wen, Shuyi Zheng, Zelong Sun, Junxin Chen, Zhangyue Zheng, Jia Wu*, Shibin Yin*
https://doi.org/10.1016/j.cjsc.2025.100697
ABSTRACT
During the HMFOR process, the Mo component in NiMo alloy undergoes a dynamic process of oxidative dissolution and re-adsorption on the catalyst surface as MoO42‒, forming a unique interface structure with the reconstructed Ni3+. The synergy of MoO42‒ and Ni3+ enhances the adsorption and activation of HMF molecules, thereby boosting the oxidation of HMF to FDCA.
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ArticleEnhancing the photocatalytic activity of crystalline g-C3N4 towards NO oxidation and CO2 reduction through K+-doping and cyano defects engineeringZhou Li, Mengxue Yu, Shixin Chang, Zhibin Huang, Zhenmin Cheng, Weibin Zhang, Sónia A.C. Carabineiro, Zhigao Xu, Kangle Lv*
https://doi.org/10.1016/j.cjsc.2025.100698
ABSTRACT
K+-doped crystalline g-C3N4 with cyano defects (CNK) was facilely synthesized using KCl as a molten salt. The material exhibits enhanced photoreactivity due to the formation of a build-in electric field. -
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ArticleLead-free organic antimony halide with dual-band intrinsic white light emission for warm WLED directlyHua Tong, Haibo Li*, Wei Liu*, Gangfeng Ouyang*
https://doi.org/10.1016/j.cjsc.2025.100678
ABSTRACT
By designing different functional units in the same structure, an organic antimony halide compound with dual-band intrinsic white light emission have been synthesized which have two emission centers comes from inorganic units and organic cations, showing potential as new solid-state lighting phosphors. -
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ReviewA comprehensive review MOFs and their derivatives as high-performance supercapacitor electrodesMalaika Arshad, Zia Ul Haq Khan*, Swera Talib, Sana Sabahat, Noor Samad Shah, Huma Ajab, Farooq Ahmad, Syed Khasim, M.A. Diab*, Heba A. El-Sabban*
https://doi.org/10.1016/j.cjsc.2025.100676
ABSTRACT
This review presents a structured analysis of mono, bi, and trimetallic MOFs and their derivatives, emphasizing their synergistic effects, synthesis strategies, and the influence of metallic composition on performance, while highlighting key structure property relationships and practical stability for next-generation energy storage systems. -
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ReviewMagnetic field controlled electrocatalysis from a multidimensional catalytic perspective: mechanisms, applications, and prospects for energy conversionShanru Feng, Ling Wen, Li Zhang, Qinyu Jiang, Bozhao Zhang, Guohao Wu, Yue Wu, Jiabin Chen*, Youcai Han*, Chuhao Liu*, Yu-Wu Zhong, Jiannian Yao*
https://doi.org/10.1016/j.cjsc.2025.100662
ABSTRACT
Multidimensional Magnetic Field Control in Electrocatalysis: Multi-Mechanism Synergy Breaks Efficiency Limits in Energy Conversion. -
ArticleDynamic tuning of d-p orbital hybridization during sulfur vacancy evolution in Co9S8 toward efficient overall water splittingWeilong Liu, Jipeng Dong, Luyao Zhang, Ning Li, Yangqin Gao, Lei Ge*
https://doi.org/10.1016/j.cjsc.2025.100661
ABSTRACT
An effective strategy to fabricate Co9S8 catalysts with optimal sulfur vacancy concentration, where vacancy evolution during reactions induces electronic redistribution that modulates d-p orbital hybridization for efficient water splitting. -
![Revisit the classical [Fe4S4(SR)4]2- molecular clusters: The steric effects of ligands and their structural transformations 2025.100660](/Site/default/Uploads/20250715/未标题-3[436].png "Revisit the classical [Fe4S4(SR)4]2- molecular clusters: The steric effects of ligands and their structural transformations 2025.100660")
ArticleRevisit the classical [Fe4S4(SR)4]2- molecular clusters: The steric effects of ligands and their structural transformationsYuhao Jin, Zheng Zhou*, Haixiang Han*
https://doi.org/10.1016/j.cjsc.2025.100660
ABSTRACT
Structural transformation behavior of classical [Fe4S4(SR)4]2- molecular clusters. -
ArticleTandem assembly-disassembly-reassembly of hierarchical Co19 coordination cluster facilitated by in-situ ligand transformation: Crystallography and ESI-MS revealed mechanismQiu-Jie Chen, Tian-Ying Gu, Zhao-Bo Hu, Man-Bo Zhang, Zheng Yin, and Ming-Hua Zeng*
https://doi.org/10.1016/j.cjsc.2025.100659
ABSTRACT
The largest cobalt and polydentate ligand based cluster featuring odd-nuclearity, namely [Co19(HL1)8(L1)12(L′)2(Ac)4], was constructed facilitated by in-situ ligand transformation. A probable assembly-disassembly-reassembly mechanism is put forward as [CoL2]→[Co4L4]→[Co7L10]→[Co13L12(L′)2]→[Co19L20(L′)2], benefited from a method integrating both crystallography and electrospray ionization mass spectrometry, thereby identifying various crucial fragments and establishing their relevance. -
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ArticleConvenient transformation of FAU zeolites to IWV aluminosilicates with adjustable Al sites for Baeyer-Villiger oxidationMeichen Jiao, Sitong Liu, Chunmin Jia, Hao Xu, Zhiguo Zhu, Peng Wu*, and Xian-Ming Zhang*
https://doi.org/10.1016/j.cjsc.2025.100654
ABSTRACT
The facile synthesis of IWV aluminosilicates with varying Al contents has been demonstrated via interzeolite transformation. This transformation employed commercial FAU zeolites as the starting materials and generated IWV aluminosilicates across a broad compositional range in either fluoride or hydroxide media. High-silica IWV aluminosilicate (Si/Al molar ratio of 54.6) exhibited superior catalytic behavior to the other IWV catalysts with higher Al contents in Baeyer–Villiger oxidation of cyclohexane. -
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ArticleEngineering optical anisotropy in paramagnetic organic crystals: Dichroism of nitronyl nitroxide radicalsMatvey K. Shurikov, Yuliana A. Kolesnikova, Darya E. Votkina, Pavel A. Abramov, Taisiya S. Sukhikh, Galina V. Romanenko, Sergey L. Veber, Dmitry E. Gorbunov, Nina P. Gritsan, Giuseppe Resnati, Evgeny V. Tretyakov, Vadim Yu. Kukushkin, Pavel S. Postnikov*, Pavel V. Petunin*
https://doi.org/10.1016/j.cjsc.2025.100653
ABSTRACT
Nitronyl nitroxide radical crystals exhibit strong linear dichroism when transition dipole moment vectors are aligned parallel on the illuminated crystal face. -
ReviewHighly active transition metal phosphides for urea oxidation: Design strategies, application advances, and perspectivesQimeng Zhu, Juan Xiao, Changyi Deng, Tingting Huang, Hui Ding, Li Zhang*, Guancheng Xu*
https://doi.org/10.1016/j.cjsc.2025.100651
ABSTRACT
Highly active transition metal phosphides are engineered via morphology engineering and electronic structure modulation, enabling efficient urea oxidation and energy applications, with future prospects for sustainable catalysis. -
ArticlePeriodic Janus structure based on ionic covalent organic framework for selective removal of perfluoroalkyl substancesXiaojuan Sun, Ke Kong, Jun Liang, Dan Wang, Beibei Dong*, Ruihu Wang*
https://doi.org/10.1016/j.cjsc.2025.100652
ABSTRACT
An ionic covalent organic framework (iCOF-DGCl) with hydrophobic aromatic moieties and hydrophilic guanidinium moieties was successfully prepared by using the Janus strategy. The iCOF exhibited fast kinetics, record capacities, high selectivity and good recyclability for the removal of toxic perfluorooctane sulfonate by cooperative adsorption. This work provides a tailor-made iCOF consisting periodic Janus structures for wastewater remediation.
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