Just Accepted
Just Accepted
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ArticleOxophilic support mediated interfacial water reconstruction on RuO2 for high-efficiency proton exchange membrane electrolysisJuan Zhu1, Jingxiang Xia1, and Wei Luo*
Acidic oxygen evolution reaction; Interfacial H2O; Hydrogen-bond network; Proton exchange membrane water electrolyzer
ABSTRACT
We demonstrated that anchoring RuO2 onto oxophilic MoO3 nanosheet promotes the connectivity of hydrogen-bond network and induces the ordered arrangement of interfacial water molecules in the electrical double layer. These water molecules serve as efficient proton-transfer mediators, accelerate the deprotonation step, facilitate rapid proton hopping, thereby leading to both enhanced catalytic activity and stability toward acidic water oxidation. -
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ArticleModulating charge kinetics in CDs/CTF S-scheme hybrids for enhanced H₂O₂ photosynthesisHaoyuan Qin, Lijing Wang, Yuanhao Tang, Weilong Shi*, Changyu Lu*
Covalent triazine frameworks; N, S-CDs; S-scheme heterojunction; H2O2; photocatalysis
ABSTRACT
The constructed N,S-CDs/CTFs S-scheme heterojunction utilizes synergistic conjugation and an internal electric field to enhance electron transfer, achieving 1.7-fold superior antibacterial activity via H2O2 production. -
ReviewMultiscale interfacial engineering of halide electrolytes for high-performance all-solid-state lithium batteriesJialiang Zhu, Yuan Zhong, Bingqing Xu*, and Gen Zhang*
ABSTRACT
This review summarizes key advances in halide solid-state electrolytes, from material design to industrial scale-up, and outlines the path toward achieving stable, high-performance batteries. -
ArticleSub-nanoscale oxygen-defect-rich MoO3-x: A versatile platform for label-free ultrasensitive SERS biodetectionXiaoyu Song1, Xinghua Liu1, Lei Xu1, Aochi Liu, Xiangyu Meng, Yuening Wang, Mingjian Zhang, Guangcheng Xi*, Jie Lin*, Xiaotian Wang*, Gengchen Xie*
ABSTRACT
MoO3-x sub-nanowires with oxygen-defect-rich were synthesized. These MoO3-x Sub-NWs SERS substrates exhibit ultrasensitive, label-free detection of environmental pollutants and enable highly accurate cancer cell classification. -
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Short CommunicationNa2(C6H4NO3)2∙H2O: A promising ultraviolet nonlinear optical crystal with strong second-harmonic generation effect and large birefringenceXuan Pang, Yongzhang Wang, Chunmei Huang*
ABSTRACT
A novel NLO crystal, Na2(C6H4NO3)2∙H2O, composed of Na+ cations and planar organic anions [C6H4NO3]–, exhibits a short UV cutoff edge below 282 nm, a strong SHG response (∼6.2× KDP), and a large birefringence (0.394 at 546.1 nm). -
ArticleUnconventional configuration of excimer in luminescent aggregates uncovered by in situ photo-difference electron densityLong-Qi Yang, Xiao-Ming Jiang*, Fa-Kun Zheng, Guo-Cong Guo*
Luminescent aggregates; Excimer; In-situ electron density; Noncovalent interactions; Light-induced structural evolution
ABSTRACT
Our experiment enables direct observation of pyrene excimer formation, identifying a unique T-shaped configuration that revises the conventional understanding of their molecular arrangement. -
ArticleFrom laboratory insights to industrial applications in continuous flow sonophotocatalytic abatement of persistent pollutants enabled by a broad-spectrum S-scheme photocatalystRajamani Manju, Ganesh Masilamani, Bernaurdshaw Neppolian*
Tetracycline; Zeolitic imidazole framework; Cobalt tungstate; Sonophotocatalytic degradation; Wastewater remediation; Continuous-flow reactor; S-scheme heterojunction.
ABSTRACT
A broad-spectrum S-scheme photocatalyst enables efficient sonophotocatalytic degradation of pharmaceutical pollutants and performs reliably in a continuous-flow system for practical wastewater treatment -
ReviewMetal-organic frameworks in perovskite solar cells: Harnessing structural diversity for enhanced photovoltaic performanceYuhao Xiong, Jian Zhang*, Yue Sun，Boyuan Hu，Wei Wang，Yuanyuan Yin, Debin Xia, Kaifeng Lin, Yulin Yang*, Evgeny Tretyakov
Metal-organic frameworks; Perovskite solar cells; Crystallization regulation; Defect passivation; Interface
ABSTRACT
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ArticleREXCO3 (RE = La, Ce, Y; X = OH, F) with circular alignment of anionic motifs induced extraordinary nonlinear optical effectsFan Liu, Pifu Gong*, Zheshuai Lin, Lei Kang*
Nonlinear optics; Second-harmonic generation; Carbonate; Ultraviolet; First-principles calculation
ABSTRACT
In accordance with the conventional structure-property relationship, the enhancement of the nonlinear optical (NLO) response of carbonates is typically achieved by regulating the parallel alignment of (CO3) groups. In rare earth carbonate series compounds, synergistic interactions occur between the circular aligned (CO3) groups and rare earth polyhedra. The interactions create extraordinary second harmonic generation (SHG) effects through electronic anisotropy and structural anisotropy. -
ArticleEngineering S-coordinated Ru single-atoms in a porphyrinic metal-organic framework for CO2 photoreductionSihong Li+, Weiping Deng+, Qijie Mo, Haili Song, Chunying Chen*, Li Zhang*
CO2 reduction; Single-atom; Metal-organic frameworks; Prphyrin; Precise chemistry
ABSTRACT
Sulfur-coordinated Ru single atoms (RuS-SAs) were precisely anchored onto the Zr6O8 clusters of a zinc porphyrinic metal–organic framework (Zn-PCN-222). The resultant composite RuS-SAs@Zn-PCN-222 exhibited high performance in CO2 photoreduction to HCOOH, owing to the electronic contributions from both Zn-PCN-222 and –SH groups to the active center Ru-SAs. -
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ArticleEngineering π-delocalized network in fused-thiophene based polymers/g-C3N4 S-scheme heterojunctions for photocatalytic H2 evolutionWeixia Wang+, Yongji Zhang+, Fei Zhao, Libo Wang, Fanpeng Meng*, Shuchao Qin*, Jinsheng Zhao*
Conjugated porous polymers; Carbon nitride; S-scheme; Photocatalytic hydrogen evolution; Extended π-delocalized network
ABSTRACT
An all-polymer S-scheme heterojunction, engineered via π–π stacking, achieves a remarkable 287-fold enhancement in photocatalytic hydrogen evolution. -
ArticleLattice solvent-modulated multicolor photochromism in a donor-acceptor type iodoargentate hybridTanlai Yu*, Le Cen, Yaxin Cheng, Guoshuai Zhang, Dayi Guo, Lei Wu, Xufeng Yang, Zhiyu Zhang, Cuilin Yang, Huan Zhang, Wenjiao Li, Yunlong Fu*, Jiang Liu*, Yong Yan*
Multicolor Photochromism; Electron donor-acceptor system; Iodoargentate hybridt; Lattice solvent-modulated; Erasable printing
ABSTRACT
A novel electron donor-acceptor (EDA)-type haloargentate hybrid, [(2-Bz-pyH)(Ag5I6)]·MeCN, has been synthesized, which was found to display rare lattice solvent-modulated multicolor photochromic performance in the same EDA system. -
Engineering 2D/2D FeOOH/BiOCl S-scheme heterojunction toward efficient and stable tetracycline photodegradationWanxin Hu, Yan Shi, Junxia Yu, Haiyang Shi*, Yingping Huang, Ruiping Li*
S-scheme heterojunction; BiOCl; Photocatalysis; Charge separation; Structural stability
ABSTRACT
Engineering FeOOH/BiOCl S-scheme heterojunction photocatalyst exhibits excellent efficiencies of photocarrier separation and TC degradation, improving the structural stability and photocatalytic activity of BiOCl. -
ReviewFluorene chemistry as a design platform for polymeric HTLs: Substituent control and core linkages in perovskite photovoltaicsYujin Li, Paramaguru Ganesan*, Abd. Rashid bin Mohd Yusoff, Simonetta Orlandi, Peng Gao*
Fluorene polymers; Polymeric HTLs; Inverted PSCs; C9 substitution; In situ polymerisation; Anchoring groups
ABSTRACT
This review highlights how C9 substitution patterns and core linkages in fluorene-based polymeric HTLs govern interfacial chemistry, charge transport, and stability, providing a structure–performance roadmap for efficient inverted perovskite solar cells -
PerspectiveDinitrogen fixation on transition metal complexes with flexible axial bondingXue-Lu Ma*, Jun-Bo Lu, Yuan Zhang, Ya-Fei Jiang, Jun Li *
ABSTRACT
This perspective illustrates how hemilabile axial bonding in transition metal complexes functions as a dynamic electron reservoir, regulating metal oxidation states and facilitating efficient dinitrogen fixation, guiding future catalyst design. -
ArticleEfficient uptake of Cs+ by a layered gallium oxalatophosphate with the clear insight into remediation mechanismWen Ma*, Tian-Yu Pan, Tian-Tian Lv, Yan-Ling Guo, Hai-Yan Sun, Rui-Ping Yang, Jun-Hao Tang, Ting-Hui Zhuang, Kai-Qiang Jing, Mei-Ling Feng*, Xiao-Ying Huang
Cesium removal; layered materials; oxalatophosphate; ion exchange; structural transformation
ABSTRACT
The efficient and selective capture of Cs+ ions is achieved by a gallium oxalatophosphonate and the capture mechanism is clearly “visualized” through single crystal structure analysis at the molecular level. -
ReviewCervical cancer imaging with organic small molecule NIR fluorophores: Design strategies and biomedical applicationsPachaiyappan Murugan*, Fang Yang, Loganathan Praburaman, Vijayapoopathi Singaravel, Meivelu Moovendhan, Chitrarasu Manikandan, Shi-Yong Liu*
ABSTRACT
In cervical cancer, rational molecular engineering of organic small molecules NIR fluorescent biomarkers enables tumor microenvironment-responsive imaging and theranostics. However, clinical translation necessitates the resolution of challenges related to stability, synthesis, specificity, and safety. -
ArticleHydrogen migration induced magnetic phase transitions in two-dimensional Fe-porphyrinoid metal-organic frameworksChao Jia, Min Ren, Yingdi Jin*, Xingxing Li*
ABSTRACT
The MOF constructed from Fe and diradical porphyrinoid molecules enables switching between ferromagnetic and ferrimagnetic states through hydrogen migration at the porphyrinoid center. -
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ReviewOrganic π-conjugated units as versatile building blocks for high-performance birefringent crystalsZhiyong Bai, Sangen Zhao*, Kang Min Ok*, Junhua Luo*
ABSTRACT
Research into high-performance birefringent crystals with birefringence values greater than 0.3 has grown rapidly in recent years. This article highlights recent progress in the development of birefringent crystals derived from organic π-conjugated building blocks. -
ReviewTMO-based SERS: Dual enhancement mechanisms and multi-functional analytical applicationsXiaoyu Song, Lei Xu, Xiangyu Meng, Yuening Wang, Mingjian Zhang, Aochi Liu, Jie Lin*, Xiaotian Wang*
ABSTRACT
TMO-based SERS uses CT and LSPR for signal enhancement, enables ultrasensitive detection of biomarkers, pollutants and catalytic intermediates, and addresses reproducibility via defect/interface engineering. -
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ArticleMOF derived Co–Mo2C heterojunctions with interfacial electronic modulation for oxygen reduction reaction and zinc-air batteriesDesheng Li#, Qin Li#, Peng Xu, Xingyu Guo, Heng Wu, Rui Liu*, Fei Tan*
ABSTRACT
MOF; Catalysis; Heterojunction; Oxygen reduction reaction; Zn-air batteries -
ReviewCrystalline porous organic frameworks: Emerging platforms for enzyme immobilization in biomedical applicationsXueting Hu, Lijia Zhao*, Tingting Liao, and Cheng-Peng Li*
ABSTRACT
This minireview summerizes the recent advancement of enzyme@COF and enzyme@HOF, particularly their chemistry and functionality, focusing on the interactions between COF and HOF and enzymes, and elaborates on the protective effects of various COF and HOF on enzymes. The construction of enzyme@COF and enzyme@HOF is of great significance for the application in biomedicine. Furthermore, this review discusses the disease diagnoses and drug delivery capabilities of enzyme@COF and enzyme@HOF as nanomedicines in diseases, and explores their potential for more applications in the medical field in the future.
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ArticleMOF-derived carbon-encapsulated ZnS/MnO porous microspheres for high-performance lithium storageJiamin Xiong1, Baiying Huang1, Yuling Zhang , Kaixin Zhou, Yuxuan Liu, Shengen Gong*, Zhiguang Xu*, Yongbo Wu, Akif Zeb*, Xiaoming Lin*
ABSTRACT
The synthetic methodology demonstrates a straightforward and efficient approach, wherein ZnS/MnO-D composites are fabricated via a sulfidation process followed by direct calcination, utilizing Zn-Mn-BDC as a sacrificial template. -
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ArticleExcitation-dependent tunable photoluminescence in CsCdCl3 all-inorganic perovskite for anti-counterfeitingGuojun Zhou#*, Qiqiong Ren#, Yanting Wang#, Nan Zhang, Yilin Mao, Pei Wang, Xian-Ming Zhang*
ABSTRACT
CsCdCl3 perovskite exhibits excitation-dependent reversible PL switching, enabled by competitive transitions between free excitons of [CdCl6]4− octahedra and self-trapped excitons of [Cd2Cl9]5− dimers. -
ReviewBorane cage hybrid supramolecular metal-organic frameworks (BSFs): Design, synthesis and gas separation performanceChengye Lou1, Yu Hu1, Yunjia Jiang*, Lingyao Wang*, Yuanbin Zhang*
ABSTRACT
This review provides an overview of the development history and design strategies of boron cage hybrid supramolecular metal-organic frameworks for gas separation.
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Short CommunicationEnhancing birefringence and second-harmonic generation response via aliovalent metal substitutionZhiwei Sun, Bingbing Wu, Xiaoli Wang, Qingran Ding*, Yanqiu Zhang, Xinjie Zhou, Sinan Tan, Ming Zhong, Sangen Zhao, Junhua Luo*
ABSTRACT
Aliovalent metal substitution effectively lowers structural dimensionality, thereby resolving the inherent birefringence-SHG trade-off.
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ArticleNuclear magnetic resonance-guided Monte Carlo/molecular dynamics structure inference for amorphous solidsKangren Kong1, Zaiqiang Ma1, Yu Yin, Zhaoming Liu, Ruikang Tang*
ABSTRACT
We introduce a REDOR-guided MC/MD workflow that converts site-specific NMR dipolar distances and angles into chemically realistic atomistic models of amorphous solids, demonstrated on amorphous calcium carbonate/phosphate. -
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ArticleUnidimensional heterostructured LSCF-GDC nanofiber film as oxygen electrode for efficient solid oxide cellWeilin Kong#, Man Lian#, Tong Sheng, Yarui Wang, Lu Zou*, Kaisheng Xia, Jian Pu, Bo Chi, Yunfeng Tian*
ABSTRACT
Ordered LSCF-GDC fibrous framework is developed for multifunctional SOCs with Rp of 0.117 Ω cm2, power density of 1.482 W cm-2, and stable CO2 electrolysis (2.30 A cm-2) at 800°C. -
ArticleInterface engineering of Co9S8/Ni3S2 heterojunction with robust stability for boosting peroxymonosulfate activationXiaohan Wang, Xue Guo, Zhuo Song, Chen Guan, Chengyu Yang, Tianyang Li, Yukun Zhu*, Yan Xu*
ABSTRACT
The interface engineering of novel Co9S8/Ni3S2 heterojunction was synthesized for efficient tylosin degradation with robust stability in the presence of peroxymonosulfate. -
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